페로브스카이트 태양 전지의 성능 저하 문제를 해결하는 방법은 무엇입니까?

Mar 18, 2022

Perovskite solar cells hold promise for improved photoelectric conversion efficiency, but they suffer from one of the biggest drawbacks—their performance degrades over time when exposed to sunlight. A team of scientists from the United States, China and South Korea wrote in the latest issue of "Nature" that they had performed a simple treatment on the surface of perovskite solar cells, solved the problem of degradation, and cleared the way for the application of thin-film solar cell technology. the biggest obstacle.

Perovskites are a group of materials that have the same atomic arrangement (crystal structure) as the mineral perovskite oxides. Metal halide perovskites, one of the "family members", are prepared for their great application potential in the field of high-efficiency and energy-saving thin-film solar cells. attention. Perovskite solar cells are much cheaper to manufacture than silicon-based solar cells, but they have one of the biggest drawbacks – their performance degrades when exposed to light for a long time. If this problem can be properly addressed, it will help solar technology. "Fly into the homes of ordinary people".

Yang Yang, the head of the latest research and a professor of materials science and engineering at the University of California, Los Angeles, explained that for solar cell defects, the common treatment method currently used by scientists is to deposit a layer of organic ions on the surface to make the surface negatively charged. While this treatment was designed to improve the energy-conversion efficiency of perovskite solar cells, it also allowed too many electrons to accumulate on the cell's surface. This destabilizes the orderly arrangement of atoms, making perovskite solar cells less and less efficient over time, ultimately rendering them uncommercial.

이 발견에 비추어 팀은 표면의 양전하 이온과 음전하 이온을 짝지어 표면 전자를 보다 중성이고 안정적으로 만들어 배터리 성능 저하를 해결할 수 있는 방법을 찾았습니다.

팀은 전지 노화를 가속화하는 조건과 전천후 태양광을 시뮬레이션하는 조건에서 처리된 태양 전지의 내구성을 테스트했습니다.{0} 결과는 전지가 초기 광전 변환 효율의 87%를 2,{3}}시간 이상 유지한 것으로 나타났습니다. 대조적으로, 동일한 조건 및 동일한 시간 동안 처리되지 않은 태양 전지의 성능은 65%로 떨어졌습니다.

"Our perovskite solar cells are among the most stable in efficiency reported to date, and our latest research lays the groundwork for the commercialization and widespread adoption of perovskite solar cell technology," said the researchers. On the basis of further developing and perfecting this technology, we can design more stable perovskite solar cells."